Tetrahedron Letters p. 703 - 706 (1999)
Update date:2022-08-16
Topics:
Cristau
Virieux
Vinylic phosphorus compounds were found to react as Michael olefins with alcohols in basic catalytic conditions. Several phosphorylated polyethers were obtained in such a way. In analogous conditions, the hydroxymethylphosphine oxide used as alcoholic reagent looses formaldehyde leading to 1,2-diphosphorus compound formation.
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