Journal of Organometallic Chemistry p. 125 - 132 (1988)
Update date:2022-08-17
Topics:
Duboudin, Francoise
Birot, Marc
Babot, Odile
Dunogues, Jacques
Calas, Raymond
The conversion of polydimethylsilanes into the corresponding polycarbosilanes has been studied using liquid monomeric catalysts such as B(OR)3 (R = Me, Pr, SiMe3) or the B-N bonded compounds: Me2BN(SiMe3)2 and B(NEt2)3.Using this route it is possible to obtain polycarbosilanes which are more stable than the Mark III synthesized by the Yajima route and have a smaller polydispersity.These precursors obtained at 380-400 deg C do not require the use of an autoclave.
Suzhou Kangrun Pharmaceutical, Inc
Contact:86-512-63912376，63913329
Address:Building 2, No. 2358 ,Chang'an Rd, Wujiang Economic Development Zone Pioneering park, china
Shanghai HengXun Pharmaceutical Tech. Co., Ltd.
Contact:86-86-52730756
Address:Room 603, No. 240, Tianmuzhong Road, Zhabei, Shanghai, China
Jiangsu Zhenfang Chemical CO.,LTD.(Suzhou Zhenfang Chemical Factory)
Contact:+86-512-69598882
Address:Room1201, Jiayuan Road No.1018, Xiangcheng District, Suzhou, China
Contact:+8613400661290
Address:No 908,Kangwan Rd, Liuyang Economic
Contact:86-512-69362780,69362785
Address:No.69 Weixin Road,Weiting Town,Suzhou Industrial Park
Doi:10.1002/ejoc.201600583
(2016)Doi:10.1016/S0006-2952(99)00309-3
(2000)Doi:10.1248/cpb.50.672
(2002)Doi:10.1021/ja103768r
(2010)Doi:10.1016/S0040-4039(97)10167-8
(1997)Doi:10.1039/b706968e
(2007)
