PREPARATION OF SUBSTITUTED BENZOYLTRIMETHYLSILANES BY THE PALLADIUM-CATALYZED SILYLATION OF SUBSTITUTED BENZOYL CHLORIDES WITH HEXAMETHYLDISILANE

DOI: 10.1016/S0040-4039(00)77777-X

Source and publish data:

Tetrahedron Letters p. 1653 - 1656 (1980)

Update date:2022-08-28

Topics:

Authors:

Yamamoto, Keiji

Suzuki, Shigeaki

Tsuji, Jiro

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Article abstract of DOI:10.1016/S0040-4039(00)77777-X

A direct preparative route to benzoyltrimethylsilane has been found by the reaction of benzoyl chloride with hexamethyldisilane in the presence of a specified palladium(II) complex as catalyst.

Full text of DOI:10.1016/S0040-4039(00)77777-X

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Product name:1-(Trimethylsilyl)-4-nitrobenzene

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