A novel preparation of cyclic sulfites through photosulfoxidation of alkenes

DOI: 10.1016/S0040-4020(01)97338-7

Source and publish data:

Tetrahedron p. 2053 - 2055 (1974)

Update date:2022-08-11

Topics:

Authors:

Jones Jones

Adelman Adelman

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Article abstract of DOI:10.1016/S0040-4020(01)97338-7

The cyclic sulfite, 4-ethyl-5-methyl-1,3,2-dioxathiolane 2-oxide, has been prepared by the photosulfoxidation of trans-2-pentene, and the quantum yield for the reaction has been determined. The proposed mechanism involves the reaction of a charge transfer complex formed between sulfur dioxide and the alkene, and is consistent with the participation of the triplet state of the former.

Full text of DOI:10.1016/S0040-4020(01)97338-7

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Product name:4,5-Dimethyl-1,3,2-dioxathiolane 2-oxide

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