Photochemical Cycloaddition of Benzophenone to 7-Methylenetetracyclo2,8.04,6>octan-3-one and its Alcohol Derivative

DOI: 10.1039/c39800000378

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Journal of the Chemical Society. Chemical communications p. 378 - 380 (1980)

Update date:2022-08-11

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Authors:

Nitta, Makoto

Kuroki, Toshio

Sugiyama, Hiroshi

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Article abstract of DOI:10.1039/c39800000378

Irradiation of benzophenone with 2,4-dimethyl- or 1,2,4-trimethyl-7-methylenetetracyclo<3.3.0.0^2,8.0^4,6>octan-3-one affords oxetans (3a) and (3b), respectively, while irradiation with the alcohol derivative (2) affords a rearranged product (5) in addition to an oxetan.

Full text of DOI:10.1039/c39800000378

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