Chemical and Pharmaceutical Bulletin p. 715 - 719 (1996)
Update date:2022-08-17
Topics:
Node, Manabu
Hao, Xiao-Jiang
Nishide, Kiyoharu
Fuji, Kaoru
A total synthesis of (-)-eserethole (2) has been accomplished using the Diels-Alder reaction of (S)-(-)-methyl-2-[2-(E)-nitroethenyl]-δ- valerolactone (3) and Danishefsky's diene as a key step. The synthesis of optically pure (-)-eserethole (2) constitutes a formal synthesis of naturally occurring Calabar bean alkaloids such as (-)-physostigmine (1), (-)- physovenine (17) and (-)-geneserine (18).
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Doi:10.1021/acs.joc.8b01517
(2018)Doi:10.1039/c1dt11377a
(2012)Doi:10.1007/s00044-011-9739-5
(2012)Doi:10.1002/jrs.3093
(2011)Doi:10.3390/molecules13040716
(2008)Doi:10.1016/S0022-328X(01)01436-X
(2002)
