Preparation of a novel carbon-based solid acid from cocarbonized starch and polyvinyl chloride for cellulose hydrolysis

Article abstract of DOI:10.1016/j.apcata.2013.12.037

A novel carbon-based solid acid was successfully prepared by sulfonation of cocarbonized starch and polyvinyl chloride (PVC). The characterization results show that this catalyst possesses all characteristics of traditional carbon-based solid acids (CSAs). The differences are that chlorine from PVC is covalently bonded to edges of aromatic carbon sheets as new active groups, and ether (C-O-C) and aliphatic (-CH₂-) bridges are formed during the cocarbonization process which are derived from oxygen in starch and alkyl in PVC, respectively. Chlorine groups can adsorb cellulose hydroxyl groups strongly and bridge bonds make the carbon framework fully stretch, which reduces hindrance between SO₃H groups and glycosidic bonds to promote the catalytic performance in cellulose hydrolysis experiments. Furthermore, the durability results indicate that this catalyst has good stability.