Journal of Chemical Thermodynamics p. 505 - 512 (1985)
Update date:2022-08-17
Topics:
Steele, William V.
Gammon, Bruce E.
Smith, Norris K.
Chickos, James S.
Greenberg, Arthur
Liebman, Joel F.
The standard molar enthalpies of combustion and sublimation for 2,3-diphenylcycloprop-2-en-1-one (C15H10O) at 298.15 K have been redetermined.The experimental values: ΔfH0m(C15H10O, cr) = (198.03 +/- 1.96) kJ*mol-1 and ΔgcrH0m(C15H10O) = (119.7 +/- 8) kJ*mol-1 yield a value for ΔfH0m(C15H10O, g) = (317.7 +/- 8.2) kJ*mol-1.If one assumes a ring strain in cycloprop-2-en-1-one of 280 kJ*mol-1, then the resonance stabilization in the three-membered ring is 88 kJ*mol-1.This indicates substantial ground-state aromatic stabilization in this molecule.
ClickChem Technology Co., Limited
Contact:+86-0310-6519966/0531-52893837
Address:No.750 Shunhua Road, High-Tech Zone, Jinan city, Shandong China
Contact:+86 512 6287 2180
Address:398 Ruoshui Road, Suzhou Industrial Park, Suzhou, Jiangsu, P. R. China
Huangshi Meifeng Chemical Co.,ltd.
Contact:+86-714-6516706
Address:1941-4-3#,Hubin Avenue,Huangshi,Hubei,China
zhejiang huangyan wanfeng pharm chem co.ltd
Contact:+86-576- 84160728
Address:No. 5 Dazha Road, Economic,Development Zone(JiangKou), Zhejiang, China
Chongqing Rong＆Quan Pharmaceutical Technology Co. , Ltd.
Contact:86-023-65268721
Address:No. 7, Manshanhong Village, Pingdingshan, Shapingba District, Chongqing Province, China
Doi:10.1016/j.ejmech.2020.112664
(2020)Doi:10.1016/S0040-4039(01)96531-1
(1971)Doi:10.1021/ja01478a052
(1961)Doi:10.1016/j.tet.2014.11.065
(2015)Doi:10.1016/j.catcom.2010.01.013
(2010)Doi:10.1055/s-1999-3412
(1999)
