Tetrahedron Letters p. 4477 - 4480 (1988)
Update date:2022-08-29
Topics:
Page, Philip C. Bulman
Klair, Sukhbinder S.
Brown, Michael P.
Harding, Marjoire M.
Smith, Christopher S.
et al.
Thiols react with alkylhalides in the presence of sodium carbonate and a catalytic quantity of (dppm)PtCl2 to give thioethers.Of especial interest is the succesful application to thioacetal formation using 1,1-dihalides which, does not require the use of strong bases or the intermediacy of thiolate anions.
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(1968)
