
Bulletin of the Chemical Society of Japan p. 603 - 604 (1984)
Update date:2022-08-11
Topics:
Matsui, Masaki
Miyamoto, Yoshihiko
Shibata, Katsuyoshi
Takase, Yoshimi
The ozonation of xanthene was studied using an oxygen stream.Ozone attacks the methylene group of xanthene via a 1,3-dipolar insertion reaction to give the hydrotrioxide intermediate, followed by a loss of singlet oxygen to form xanthydrol.The ozonation of xanthydrol gave singlet oxygen, water and xanthone accompanied by autoxidation.
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