Tetrahedron Letters p. 651 - 654 (1998)
Update date:2022-08-11
Topics:
Maki, Toshihide
Fukae, Kazuhiro
Harasawa, Hitomi
Ohishi, Takahiro
Matsumura, Yoshihiro
Onomura, Osamu
A new electrochemical method for a selective oxidation of 1,2-diols to keto alcohols was explored. The method used dibutyltin oxide and bromide ion as mediators, and the oxidation was found to proceed effectively at 0°C under neutral conditions. Under these reaction conditions, 1,2-cyclohexanediol was selectively oxidized even in the presence of primary and secondary alcohols.
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