Selective Formation of Propyne by Protonation of an Allyl Complex

DOI: 10.1039/c39930000474

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 474 - 476 (1993)

Update date:2022-08-23

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Authors:

Oglieve, Kay E.

Henderson, Richard A.

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Article abstract of DOI:10.1039/c39930000474

Treatment of 3-C3H5)(Ph2PCH2CH2PPh2)2> with a large excess of anhydrous HCl in tetrahydrofuran rapidly yields and propyne, at low concentrations of acid, propene is formed; the mechanism of these reactions has been established by detailed kinetic studies and product analyses.

Full text of DOI:10.1039/c39930000474

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