Construction of a tube-like molecule via sequential cyclopropylidene dimerisation and intramolecular [π2s+π2s] cycloaddition reactions

DOI: 10.1039/CC9960001469

Source and publish data:

Chemical Communications p. 1469 - 1470 (1996)

Update date:2022-08-17

Topics:

Authors:

Banwell, Martin G.

Hockless, David C. R.

Walter, Justine M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/CC9960001469

The syn-cyclopropylidene dimer 5, obtained by reaction of compound 4 with methyllithium, is readily elaborated to the bis-p-benzoquinone 7 which undergoes intramolecular [π2s+π2s] cycloaddition to give the tube-like molecule 8.

Full text of DOI:10.1039/CC9960001469

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:5,8-DIMETHOXY-1,4-DIHYDRO-NAPHTHALENE

Cas No:55077-79-7

R&D Labs maybe for 55077-79-7

HANGZHOU GOPHER CHEM-TECH CO.,LTD

Contact:86-189-58111780

Address:Da Cheng Ming Zuo Plaza,Xiaoshan District
Xi'an HO-SHINE Bio-Technology Co., Ltd

Contact:+86 (29) 8248-5435/18292020086

Address:No.6 Shiyuan Road Xian City Shaanxi Province, 710048 China
Suzhou Credit International Trading Co., Ltd

Contact:+86-512-65398039

Address:Qingdeng, Hightech. District, Suzhou
ORCHID CHEMICAL SUPPLIES LTD

website:http://www.orchid-chem.com

Contact:+86-571-85395792

Address:607, North Zhongshan Road, Hangzhou 310000 China
Ceresking Ecology & Technology co.,ltd

Contact:86 22 66218397

Address:Room 1613, Zheshang Mansion, No. 1988, Yingbin Avenue, Binhai New District, Tianjin,China.

Relevant to this article

Copper ferrite nanoparticle modified starch as a highly recoverable catalyst for room temperature click chemistry: Multicomponent synthesis of 1,2,3-triazoles in water

Doi:10.1039/c7nj03284f
(2018)
1,3-Oxathiole and Thiirane Derivatives from the Reactions of Azibenzil and α-Diazo Amides with Thiocarbonyl Compounds

Doi:10.1002/hlca.19980810209
(1998)
Doi:10.1017/S0317167100001712
(1923)
Photosensitized oxidation, by single-electron transfer, of catharanthine and vindoline: A highly regio- And diastereoselective photocyanation reaction

Doi:10.1039/b001114m
(2000)
Mechanistic rationale for the NaBH₄ reduction of α-keto esters

Doi:10.1016/S0040-4039(99)01006-0
(1999)
Identification of synthetic regioisomeric lutein esters and their quantification in a commercial lutein supplement

Doi:10.1021/jf070357n
(2007)

Article Doi