Construction of a tube-like molecule via sequential cyclopropylidene dimerisation and intramolecular [π2s+π2s] cycloaddition reactions

DOI: 10.1039/CC9960001469

Source and publish data:

Chemical Communications p. 1469 - 1470 (1996)

Update date:2022-08-17

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Authors:

Banwell, Martin G.

Hockless, David C. R.

Walter, Justine M.

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Article abstract of DOI:10.1039/CC9960001469

The syn-cyclopropylidene dimer 5, obtained by reaction of compound 4 with methyllithium, is readily elaborated to the bis-p-benzoquinone 7 which undergoes intramolecular [π2s+π2s] cycloaddition to give the tube-like molecule 8.

Full text of DOI:10.1039/CC9960001469

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