Journal of Physical Organic Chemistry p. 192 - 195 (1994)
Update date:2022-08-10
Topics:
Pires, Jose Ricardo
Stachissini, Antonia Sonia
Amaral, Luciano Do
The secondary α-deuterium isotope effect on the equilibrium constant (KD/KH) for the hydration of p-nitrobenzaldehyde is 1.39 +/- 0.05.The kinetic secondary α-deuterium isotope effect (kD/kH) for the addition of water to p-nitrobenzaldehyde is 1.18+/-0.07.This result demonstrates that there is extensive carbon-oxygen bond formation in the transition state for addition of water to the carbonyl group of p-nitrobenzaldehyde.
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