Journal of Organometallic Chemistry p. 359 - 364 (1983)
Update date:2022-08-17
Topics:
Hoberg, Heinz
Oster, Benno W.
Diphenylacetylene and phenylisocyanate react with TMEDA/Ni0 to give an azanickela-5-ring (IVa) which yields the azanickela-7-ring (IIb) with an activated alkyne.It is shown that both IVa and IIb are intrmediates in the nickel-catalysed 2-pyridone synthesis.Pyrimidinediones are formed from diphenylacetylene and alkylisocyanates with TMEDA/Ni0.
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