Chemistry Letters p. 743 - 744 (1999)
Update date:2022-08-11
Topics:
Zen, Jyh-Myng
Senthil Kumar, Annamalai
Chen, Jyh-Cheng
The electrocatalytic oxidation of cysteine (CySH) to cystine (CyS-SCy) was noticed on the Nafion-ruthenium oxide pyrochlore chemically modified electrode. The electrocatalytic oxidation was mediated by the RuVI/IV redox sites in the oxide pyrochlore network in terms of the Michaelis-Menten kinetics. The obtained heterogeneous catalytic rate constant (kc) and transfer coefficient (α) are 6.33 s-1 and 0.99, respectively.
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