Oxidation of an αβ-(epoxyalkyl) trimethylsilane with pyridine oxides in the presence of silylating agents. A facile enantioselective synthesis of glyceraldehyde derivatives

DOI: 10.1016/S0040-4039(00)76915-2

Source and publish data:

Tetrahedron Letters p. 3387 - 3390 (1994)

Update date:2022-08-16

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Authors:

Raubo, Piotr

Wicha, Jerzy

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Article abstract of DOI:10.1016/S0040-4039(00)76915-2

Trimethylsilyl glycidol derivatives 1 were oxidized with pyridine N-oxides in the presence of silylating agents to give the corresponding glyceraldehyde derivatives 3. Reaction of (α,β-epoxyalkyl)silanes with N-oxides was studied.

Full text of DOI:10.1016/S0040-4039(00)76915-2

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