Oxidation of an αβ-(epoxyalkyl) trimethylsilane with pyridine oxides in the presence of silylating agents. A facile enantioselective synthesis of glyceraldehyde derivatives

DOI: 10.1016/S0040-4039(00)76915-2

Source and publish data:

Tetrahedron Letters p. 3387 - 3390 (1994)

Update date:2022-08-16

Topics:

Authors:

Raubo, Piotr

Wicha, Jerzy

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)76915-2

Trimethylsilyl glycidol derivatives 1 were oxidized with pyridine N-oxides in the presence of silylating agents to give the corresponding glyceraldehyde derivatives 3. Reaction of (α,β-epoxyalkyl)silanes with N-oxides was studied.

Full text of DOI:10.1016/S0040-4039(00)76915-2

Products guided by the article

Product name:2-Acetylpropane

Cas No:563-80-4

R&D Labs maybe for 563-80-4

Hefei Leaf Biotech Co., Ltd.

Contact:86-551-62628115

Address:No 36 Chuangye Road,Xuancheng Economic and Technological Development Zone,Anhui Province,P.R.China
Shanghai Synmedia Chemical Co., Ltd

Contact:+86-21-38681880

Address:6th Floor, 11A Building, No.528 Ruiqing Road, Heqing town, Pudong new district, Shanghai China
Hangzhou Haichem Co.,Ltd.

Contact:+86-571-86025531 / 86024803

Address:1218-24 Guangyin Mansion,42 Fengqi East Road
Zhengzhou Minzhong Pharmaceutical Co.,ltd

Contact:0086-371-65797115

Address:15/F,Jiangshan Bldg, NO.126 Huanghe Road,Zhengzhou, China
Lyan Limited

Contact:86-021-52418058

Address:8/F, Building 6, Guiping Road No.333, Shanghai, 200233, China

Relevant to this article

New rhodacarborane-phosphoramidite catalyst system for enantioselective hydrogenation of functionalized olefins and molecular structure of the chiral catalyst precursor [3,3-{(S)-PipPhos}₂-3-H-1,2-(o -xylylene)- closo -3,1,2-RhC₂B

Doi:10.1021/om101201e
(2011)

Design, synthesis, and biological evaluation of some novel indolizine derivatives as dual cyclooxygenase and lipoxygenase inhibitor for anti-inflammatory activity

Doi:10.1016/j.bmc.2017.06.027
(2017)
Doi:10.1021/ja01650a077
(1954)
Heterostructured composites consisting of In₂O₃ nanorods and reduced graphene oxide with enhanced interfacial electron transfer and photocatalytic performance

Doi:10.1039/c4ta04106b
(2014)
L-proline in an ionic liquid as an efficient and reusable catalyst for direct asymmetric aldol reactions

Doi:10.1016/S0040-4039(02)02104-4
(2002)
Doi:10.1021/ja00750a056
(1971)

Article Doi