Journal of the Chemical Society. Chemical communications p. 783 - 784 (1983)
Update date:2022-08-16
Topics:
Grimshaw, James
Moore, Shirley
Thompson, Norris
Trocha-Grimshaw, Jadwiga
Certain 1-alkyl-2,4,6-trisubstituted pyridinium salts form ?-radicals by electrochemical reduction which are stable in dimethylformamide on the time scale of cyclic voltammetry, whereas the corresponding 1-benzyl and 1-allyl compounds undergo carbon-nitrogen bond cleavage at measured rates which are dependent on the size of the 2,6-substituents.
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