Chemistry Letters p. 717 - 718 (1995)
Update date:2022-08-16
Topics:
Yamaguchi, Masatsugu
Shido, Takafumi
Ohtani, Hiroko
Isobe, Kiyoshi
Ichikawa, Masaru
Silica-supported <(RhCp*)4V6O19 exhibited high catalytic activities in the gas-phase hydration of acetonitrile towards acetamide at 350-473 K with selectivity of over 97percent and dehydrogenation of 2-propanol to acetone.EXAFS, XPS and FTIR studies suggested that thermal evacuation of silica-supported <(RhCp*)4V6O19> at 473 K led to the removal of the bridged oxygen atoms in the V6O19 framework.The resulting deoxygenated samples enhanced the acetonitrile hydration, while catalyzed the dehydration of 2-propanol to propene besides the dehydrogenation reaction, probably owing to the newly generated Lewis acid site.
View More
Suzhou Ryan Pharmachem Technology Co.,Ltd
Contact:+86-0512-68780025
Address:B-301,No.2 Taishan Road,Suzhou New District,Jiangsu,P.R. China
Dongying J&M Chemical Co., Ltd,
Contact:546-8551108
Address:Room 1219, Zisheng Mansion, Zibo Road, Dongying, Shandong, China
Quzhou Aokai Chemical Co., Ltd.
Contact:86-570-3032832
Address:NO.16 , Laodong Road,Quzhou City, Zhejiang Province,China
Shandong Xinhua Pharmaceutical Co.,Ltd
website:http://www.xhzy.com
Contact:+86-533-2196801
Address:1 lutai road,zhangdian dis,Zibo City
Improve Medical Technology(Nanxiong) Co., Ltd
Contact:86-751-3836997
Address:No.33, Pingan First Road, Fine Chemical Industry Base, Nanxiong City, Shaoguan, Guangdong, China
Doi:10.1021/jm501276u
(2014)Doi:10.1016/j.bbagen.2016.04.004
(2016)Doi:10.1002/hlca.19680510220
(1968)Doi:10.1016/j.catcom.2019.02.017
(2019)Doi:10.1039/C3972000623b
(1972)Doi:10.1055/s-2007-980343
(2007)
