PARA-PREFERENTIAL ANODIC CHLORINATION OF ALKOXYBENZENES

DOI: 10.1246/cl.1981.661

Source and publish data:

Chemistry Letters p. 661 - 662 (1981)

Update date:2022-08-30

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Authors:

Matsuda, Yoshiharu

Hayashi, Hiroyasu

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Article abstract of DOI:10.1246/cl.1981.661

Anodic chlorination of methoxy- and ethoxybenzenes yielded p-alkoxychlorobenzenes preferentially.The p-/o- ratios were 34.5 in N,N-dimethylacetamide-LiCl and 17.1 in N,N-dimethylformamide-LiCl.In the former case, the current efficiency for producing p-chloromethoxybenzene was 95.8percent at Pt anode.

Full text of DOI:10.1246/cl.1981.661

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