Journal of Organometallic Chemistry p. 45 - 50 (1980)
Update date:2022-08-31
Topics:
Gambaro, Alessandro
Peruzzo, Valerio
Plazzogna, Gualtiero
Tagliavini, Guiseppe
Mixed allylbutyltin halides (CH2=CHCH2)SnBu3-nCln (n=0-3) have been prepared, and characterized by carbon-13 NMR spectroscopy.Their ability to bring about allylstannylation of ketones and aldehydes, to form organostannoxy compounds, Bu3-nSnClnOC(R')(R'')CH2CH=CH2, has been shown to increase on increasing the value of n, that is on increasing the acceptor ability of the tin centre.
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