Journal of Physical Chemistry p. 7 - 9 (1983)
Update date:2022-08-16
Topics:
Niki, H.
Maker, P. D.
Savage, C. M.
Breltenbach, L. P.
UV and IR absorption cross sections were measured for methyl thionitrite at 298 K.This compound was found to undergo photochemical reactions in the wavelength region of 300-400 nm via CH3SNO + hν -> CH3S + NO followed by CH3S + NO -> CH3SNO and 2CH3S -> CH3SSCH3.Preliminary results on the mechanism of the reaction of CH3S with O2 were also obtained.
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