THE NITRATION OF PIVALOPHENONE WITH NITRONIUM TETRAFLUOROBORATE IN SULFOLANE

DOI: 10.1016/S0040-4020(01)88365-4

Source and publish data:

Tetrahedron p. 2707 - 2714 (1990)

Update date:2022-08-11

Topics:

Authors:

Zieger, Herman E.

Lee, Brendan

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Article abstract of DOI:10.1016/S0040-4020(01)88365-4

The nitration of pivalophenone (2,2-dimethyl-1-phenylpropan-1-one) with NO2BF4 gives o-, m-, and p-nitropivalophenones in the percentage ratio of 26:45:29.Competition experiments showed that pivalophenone is ten to twenty times less reactive than benzene

Full text of DOI:10.1016/S0040-4020(01)88365-4

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