The Stereochemical Course of Substitution of Sulfur by Oxygen Nucleophiles in Five-membered Cyclic Phosphorothioates

DOI: 10.1039/c39940001947

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1947 - 1948 (1994)

Update date:2022-08-16

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Authors:

Lowe, Gordon

Thelin, Mats

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Article abstract of DOI:10.1039/c39940001947

The replacement of non-bridging sulfur in five-membered cyclic phosphorothioates by oxygen nucleophiles in the presence of bromine occurs with retention of configuration and has allowed the 31P NMR signals of the diastereoisomeric tert-butyldiphenyl silyl esters of 2',3'-cyclic adenosine monophosphate to be assigned.

Full text of DOI:10.1039/c39940001947

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