Journal of the Chemical Society. Chemical communications p. 1353 - 1355 (1990)
Update date:2022-08-30
Topics:
Ishikawa, Masashi
Fukuzumi, Shunichi
An acid-stable NADH model compound, 9,10-dihydro-10-methylacridine (AcrH2) efficiently reduces acetaldehyde and analogues in the presence of HClO4 in acetonitrile to yield 10-methylacridinium ion and the corresponding alcohols; rates of the acid-catalysed reduction of various aliphatic aldehydes and ketones by AcrH2, which have small primary kinetic isotope effects (kH/kD < 2.0), are well correlated with those of the acid-catalysed electron transfer from the excited state of
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