Journal of Organometallic Chemistry p. 303 - 309 (1981)
Update date:2022-08-17
Topics:
Deschamps, Claire
Zador, Miklos
The kinetics of oxidation of phenylacetylene by thallium(III) has been studied in aqueous solution.The reaction proceeds by two consecutive steps: rapid formation of an intermediate oxythallation compound, C6H5C(OH)=CHTl2+, followed by its much slower oxidative decomposition.The kinetics and mechanism of these reactions are discussed and compared to those observed in thallic ion oxidation of styrene.
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