ACS Catalysis p. 5233 - 5239 (2018)
Update date:2022-08-16
Topics:
Wang, Lin
Ertem, Mehmed Z.
Murata, Kazuhisa
Muckerman, James T.
Fujita, Etsuko
Himeda, Yuichiro
An efficient catalytic system using a water-soluble iridium complex, Cp?IrL(OH2)2+ (Cp? = pentamethylcyclopentadienyl, L = 2,2′,6,6′-tetrahydroxy-4,4′-bipyrimidine), was developed for highly selective methanol production at room temperature (initial turnover frequency of 4120 h-1) with a very high yield (93%). This catalytic system features paraformaldehyde as the sole carbon and hydride source, leading to a record turnover number of 18200 at 25 °C. A step-by-step mechanism has been proposed for the catalytic conversion of paraformaldehyde to methanol on the basis of density functional theory (DFT) calculations. The proposed pathway holds the potential capacity to extend the scope of indirect routes for methanol production from CO2.
View MoreAnhui New Star Pharmaceutical Development Co., Ltd
Contact:013956922763
Address:Floor 3, F9A, F Workshop, No.110 Kexue Road, High-Tech Development Zone, Hefei, Anhui ,China
Zhongshan Haihong Medicine Co., Ltd.
Contact:86-0760-86925778 (0)18824993998
Address:A7 building,lianyuan road Torch Hi-tech Industrial Development Zone
Hebei Tianxiang Biological & Pharmaceutical Co., Ltd
Contact:86-0312-6615158
Address:No 42 fazhan street qingyuan county
Onlychem (Jinan)Biotech Co.,Ltd
Contact:86-531-83175885
Address:No. 44, Honglou South Road, Jinan,China
Shaanxi Lighte Optoelectronics Material Co., Ltd.
Contact:+86-29-88320728-622/619/620
Address:No.55 INDUSTRY ROAD 2,XI'AN NATIONAL CIVIL AEROSPACE INDUSTRIAL PARK.XI'AN China 710065.
Doi:10.1016/j.tetlet.2011.02.065
(2011)Doi:10.1039/C6RA28102H
(2017)Doi:10.1021/acs.cgd.0c00961
(2020)Doi:10.1063/1.2730581
(2007)Doi:10.3762/bjoc.13.166
(2017)Doi:10.1021/ja00270a063
(1986)