A Molecular Switch for Control of Conformation: Strained Intramolecular Co-ordination in 4,4'-Bipyridyl-capped Zinc Porphyrins

DOI: 10.1039/c39840000854

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 854 - 856 (1984)

Update date:2022-08-30

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Authors:

Leighton, Philip

Sanders, Jeremy K. M.

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Article abstract of DOI:10.1039/c39840000854

Intramolecular co-ordination between the nitrogens of the cap and the central metal ion in the title compounds forces the porphyrin and bipyridyl groups to be perpendicular: addition of an external ligand releases the bipyridyl ligand which then lies parallel to the porphyrin.

Full text of DOI:10.1039/c39840000854

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