Carbanionic displacement reactions at phosphorus: Diethyl (2-pyridyl)methylphosphonate synthesis

Article abstract of DOI:10.1080/10426509708044210

We describe the formation and reactions of the α-lithiated (2-pyridyl)methylphosphonate 1. The lithiated α-picoline is obtained by metallation in THF at low temperature with LDA (lithium diisopropylamide) (2 equiv.). This is then condensed with diethyl ch

Full text of DOI:10.1080/10426509708044210

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Phosphorus, Sulfur, and Silicon and the
Related Elements
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CARBANIONIC DISPLACEMENT REACTIONS
AT PHOSPHORUS: DIETHYL (2-PYRIDY
L)METHYLPHOSPHONATE SYNTHESIS
a
a
a
John Carran , Rachel Waschbüsch & Philippe Savignac
a
Laboratoire Hétéroéléments et Coordination , UMR CNRS 7653, DCPH,
Ecole Polytechnique , 91128, Palaiseau Cedex, France Phone: (+33) 01
69 33 45 79 Fax: (+33) 01 69 33 45 79
Published online: 04 Oct 2006.
To cite this article: John Carran , Rachel Waschbüsch & Philippe Savignac (1997) CARBANIONIC
DISPLACEMENT REACTIONS AT PHOSPHORUS: DIETHYL (2-PYRIDY L)METHYLPHOSPHONATE
SYNTHESIS, Phosphorus, Sulfur, and Silicon and the Related Elements, 123:1, 209-218, DOI:
10.1080/10426509708044210
To link to this article: http://dx.doi.org/10.1080/10426509708044210
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