Tetrahedron p. 5755 - 5760 (1985)
Update date:2022-08-28
Topics:
Faller, J. W.
Lambert, C.
The stereochemistry and regiochemistry of nucleophilic addition to olefinic, allylic, or diene moieties can be controlled in reactions of molybdenum complexes.The synthesis of a wide range of α-allylic cyclohexanones is feasible using (η5-cyclopentadienyl)Mo(CO)(NO)(allyl) cations.The stereoselective preparation of (RS,SR)-2-(1-methyl-2-butenyl)cyclohexanone from the reaction of 1-pyrrolidino-1-cyclohexene with (CpMo(CO)(NO)(η3-1,3-dimethylallyl))BF4 illustrates the methodology.
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