Journal of the Chemical Society. Chemical communications p. 1429 - 1430 (1989)
Update date:2022-08-17
Topics:
Harada, Toshiro
Matsuda, Yasuhiro
Uchimura, Junji
Oku, Akira
Reaction of secondary allyl vinyl ether with ThexBH2 (Thex = 1,1,2-trimethylpropyl) followed by treatment with alkaline hydrogen peroxide gave the corresponding 1,3-diol with high syn selectivity (>16:1) with respect to the pre-existing stereogenic centre and the adjacent one.
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