
Applied Physics Letters p. 425 - 427 (1994)
Update date:2022-08-29
Topics:
Han, Jaesung
Jensen, Klavs F.
Senzaki, Yoshihide
Gladfelter, Wayne L.
Laser assisted chemical vapor deposition (LCVD) with dimethylethylamine alane (DMEAA), having more advantage of being a liquid, as compared to the solid trimethylamine alane (TMAA), was investigated in rendering high purity Al. In this study, Al pattern was nucleated by pyrolitic LCVD at a high scan speed, and the nucleated pattern was consequently selectively developed by thermal CVD. Microscopic evidence revealed high purity Al lines achieved with increasing laser power. This was further elucidated by modified Arrhenius plot showing growth rates of Al on various substrates as a function of maximum temperature rise induced by the laser. The resulting Al deposits had no measurable O and C impurities, and the resistivity was around 1.5 times that of bulk Al.
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