Journal of the Chemical Society - Faraday Transactions p. 1029 - 1032 (1994)
Update date:2022-08-30
Topics:
Ziolek, Maria
Saur, Odette
Lamotte, Jean
Lavalley, Jean-Claude
An FTIR study shows that methanethiol is adsorbed dissociatively on ZrO2 leading to thiolate species and associatively, giving rise to H-bonded and coordinated species, less stable than the CH3S- species.Only coordinated and H-bonded species are formed by dimethyl sulfide adsorption.Heating in the presence of a gas phase shows that, besides the dismutation of CH3SH into (CH3)2S and H2S, side reactions occur on the surface leading to methoxy and formate species.
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