
Journal of Organometallic Chemistry p. 149 - 160 (1983)
Update date:2022-08-11
Topics:
Blunden, Stephen J.
The ultraviolet degradation of the methyltin chlorides in carbon tetrachloride and water has been quantitatively studied by 1H NMR spectroscopy.In the organic solvent trimethyltin chloride degraded to an inorganic tin species, via di- and mono-methyltin intermediates; in water, a monomethyltin derivative was not observed.The ultraviolet breakdown of dimethyltin dichloride and monomethyltin trichloride in these solvents was also studied, and the approximate relative rates of degradation were established.
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