In44 mit In4-Tetraeder und In4Se44 mit In4Se4-Heterocubanstruktur

DOI: 10.1016/0022-328X(95)05399-A

Source and publish data:

Journal of Organometallic Chemistry p. C1 - C5 (1995)

Update date:2022-08-30

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Authors:

Uhl, Werner

Graupner, Rene

Layh, Marcus

Schuetz, Uwe

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Article abstract of DOI:10.1016/0022-328X(95)05399-A

The reaction of In^IBr with LiC(SiMe3)3*2THF yields the In(I) alkyl In44 1 in 70percent yield. 1 was characterized by a crystal structure determination showing a nearly undistorted In4 tetrahedron with mean In-In distances of 300.2(1) pm.Reaction of 1 with elemental Se gives In4Se44 2 with a slightly distorted In4Se4 hetero cubane structure.Keywords: Indium; Tetrahedron; X-ray structure; Cluster; Selenium; Heterocubane

Full text of DOI:10.1016/0022-328X(95)05399-A

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