
Journal of the Chemical Society. Chemical communications p. 567 - 569 (1984)
Update date:2022-08-16
Topics:
Ikeda, Osamu
Fukuda, Hiroshi
Tamura, Hideo
Heat-treatment of chloro(tetraphenylporphyrinato)iron(III) (ClTPPFeIII) in an Ar atmosphere gives a product with an anomalously high molar magnetic susceptibility, and on it the cathodic reduction of oxygen occurs through a 4-electron pathway, namely oxygen to water.
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