Transition Metal-Diene Complexes in Organic Synthesis - 13. Highly Chemo- and Stereoselective Oxidations of Tricarbonyliron-Cyclohexadiene Complexes: Synthesis of 4-Deoxycarbazomycin B

DOI: 10.1016/S0040-4020(01)80328-8

Source and publish data:

Tetrahedron p. 841 - 862 (1993)

Update date:2022-08-10

Topics:

Authors:

Knoelker, Hans-Joachim

Bauermeister, Michael

Pannek, Joern-Bernd

Blaeser, Dieter

Boese, Roland

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Article abstract of DOI:10.1016/S0040-4020(01)80328-8

Chemo- and stereoselectivity in oxidations of tricarbonyl<5-aryl-η⁴-cyclohexa-1,3-diene>iron complexes is achieved by the choice of the oxidizing reagent.This procedure provides iron-complexed 4a,9a-dihydro-9H-carbazoles, 4b,8a-dihydrocarbazol-

Full text of DOI:10.1016/S0040-4020(01)80328-8

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