Activation of Dioxygen and Catalytic Oxidation of Ethanol to Acetaldehyde and Hydrogen Peroxide by Copper(I) Complexes containing 2,2'-Bipyridyl and Tertiary Phosphine Ligands

DOI: 10.1039/DT9810002585

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2585 - 2586 (1981)

Update date:2022-08-10

Topics:

Authors:

Bhaduri, Sumit

Sapre, Niteen Y.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9810002585

Reactions of (bipy=2,2'-bipyridyl; L=PPh3, PMePh2, PBuⁿ3, or PEt3) with O2 alone in dimethylformamide and SO2 plus O2 in dichloromethane lead to the formation of I2 and precipitation of Cu.The complex catalyses the oxidation of ethanol by dioxygen to acetaldehyde and H2O2 in the presence of equimolar quantities of Na.Added phosphine acts as a strong inhibitor and the catalytic decomposition of H2O2 by the complexes leads to their deactivation.A tentative reaction mechanism is discussed.

Full text of DOI:10.1039/DT9810002585

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Copper sulfate pentahydrate

Cas No:7758-99-8

R&D Labs maybe for 7758-99-8

Zouping Fuhai Technology Development Co., Ltd.

Contact:+0532-86934525 18660293207

Address:jiuhu town industrial park Zouping County,bingzhou Provincejiuhu town industrial park
Shanghai Harvest Chemical Ind. Co., Ltd.

Contact:021-51385350

Address:ROOM 806-807, AI LI CHEN BUILDING, No.333 JINGXIANG ROAD, PUDONG DISTRICT, 201206, SHANGHAI
Shanghai Yuantai Chemical Products Co., Ltd

Contact:021--66129803

Address:Chengyin Road,Shanghai,China
KINHENG CHEMICAL(SHANGHAI)CO., LTD.

Contact:+8621-60490170

Address:Room401, No.28,Lane 189, Yangshupu Rd. Shanghai, China.
Jiangxi Province Bethel Pharmaceutical Co., Ltd.

Contact:+86-795-259 3456 ，+86-15957688008 13566650571

Address:Huangjindui Chemical Park， Shanggao County ，Yichun city，Jiangxi Province

Relevant to this article

Spontaneous reactions and reduction by iodide of peroxynitrite and peroxynitrate: mechanistic insight from activation parameters

Doi:10.1021/jp971506f
(1997)
Doi:10.1021/jo01258a063
(1969)
Phase evolution and kinetics of the oxidation of monosulfide solid solution under isothermal conditions

Doi:10.1016/j.tca.2004.08.007
(2005)
Synthesis and Avidin Binding of Ruthenium Complexes Functionalized with a Light-Cleavable Free Biotin Moiety

Doi:10.1002/ejic.201800644
(2018)
Sulfated mesoporous Au/TiO₂ spheres as a highly active and stable solid acid catalyst

Doi:10.1039/c2jm16921e
(2012)
Optimized preparation of CALB-CLEAs by response surface methodology: The necessity to employ a feeder to have an effective crosslinking

Doi:10.1016/j.molcatb.2012.04.013
(2012)

Article Doi