Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 2597 - 2604 (1983)
Update date:2022-08-23
Topics:
Pratt, Graham L.
Wood, Stephen W.
The reaction of hydrogen atoms (1E-6-1E-5mol dm-3) with oxygen (0-1E-5mol dm-3) in excess argon has been studied in a fast flow-discharge tube at total pressures from 2 to 10 Torr and temperatures from 231 to 512 K using mass spectrometry and gas chromatography for final-product analysis.A method of measuring small concentrations of water (ca. 1E-7mol dm-3) has been developed which enabled the relative rates of reactions (2) and (3) to be determined, reaction (4) being negligible:+Ar->HO2+Ar (1); H+HO2->(2); H+HO2->2OH (3); H+HO2->H2O+O.Over the range 231
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