Near threshold photofragmentation dynamics of ICl-Ne A state van der Waals complexes

Article abstract of DOI:10.1063/1.454644

The nascent ICl product state distribution is examined following vibrational predissociation of ICl-Ne A(ν_A=23) complexes via an optical-optical double resonance technique.ICl fragments are produced in approximately equal proportion in the ν_A=22 and 21 levels of the A(³Π₁) state.Low rotational levels of ICl A(ν_A=22) are primarily populated, J_A=1-8, accesing only a small portion of allowed states.ICl A(ν_A=21) fragments are produced with up to 69 cm^-1 of rotational energy in a broad distribution which extends to nearly the energetic limit.Homogeneous broadening of the ICl-Ne feature indicates a vibrational predissociation lifetime between 2.3 and 50 ps.

Full text of DOI:10.1063/1.454644

Near threshold photofragmentation dynamics of ICl–Ne A state van der Waals
complexes
Janet C. Drobits and Marsha I. Lester
Citation: The Journal of Chemical Physics 88, 120 (1988); doi: 10.1063/1.454644
View online: http://dx.doi.org/10.1063/1.454644
View Table of Contents: http://scitation.aip.org/content/aip/journal/jcp/88/1?ver=pdfcov
Published by the AIP Publishing
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152.2.176.242 On: Sun, 30 Nov 2014 14:25:03

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
152.2.176.242 On: Sun, 30 Nov 2014 14:25:03

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
152.2.176.242 On: Sun, 30 Nov 2014 14:25:03

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
152.2.176.242 On: Sun, 30 Nov 2014 14:25:03

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
152.2.176.242 On: Sun, 30 Nov 2014 14:25:03

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
152.2.176.242 On: Sun, 30 Nov 2014 14:25:03

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
152.2.176.242 On: Sun, 30 Nov 2014 14:25:03

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
152.2.176.242 On: Sun, 30 Nov 2014 14:25:03