Chemistry Letters p. 615 - 618 (1981)
Update date:2022-08-16
Topics:
Somei, Masanori
Yamada, Fumio
Karasawa, Yoshio
Kaneko, Chikara
Ergot alkaloid, (+/-)-6,7-secoagroclavine was synthesized form 2-methyl-5-nitroisoquinolinium iodide by three routes.In the course of the study, a novel intra-molecular γ-alkylation of allyl alcohol was found.Reaction of Grignard reagents with nitroalkanes to afford N-alkyl hydroxylamines was effectively used in the present synthesis.
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Doi:10.1016/j.saa.2007.12.051
(2008)Doi:10.1016/0031-9422(81)83050-6
(1981)Doi:10.1039/b406906d
(2004)Doi:10.1016/S0968-0896(99)00248-5
(1999)Doi:10.3390/molecules23020433
(2018)Doi:10.1016/S0008-6215(00)85292-1
(1981)
