TOTAL SYNTHESIS OF ERGOT ALKALOID, (+/-)-6,7-SECOAGROCLAVINE

DOI: 10.1246/cl.1981.615

Source and publish data:

Chemistry Letters p. 615 - 618 (1981)

Update date:2022-08-16

Topics:

Authors:

Somei, Masanori

Yamada, Fumio

Karasawa, Yoshio

Kaneko, Chikara

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1981.615

Ergot alkaloid, (+/-)-6,7-secoagroclavine was synthesized form 2-methyl-5-nitroisoquinolinium iodide by three routes.In the course of the study, a novel intra-molecular γ-alkylation of allyl alcohol was found.Reaction of Grignard reagents with nitroalkanes to afford N-alkyl hydroxylamines was effectively used in the present synthesis.

Full text of DOI:10.1246/cl.1981.615

Products guided by the article

Product name:Methyl-[(4S,5S)-5-(2-methyl-propenyl)-1,2,2a,3,4,5-hexahydro-benzo[cd]indol-4-yl]-amine

Cas No:79139-01-8

R&D Labs maybe for 79139-01-8

AstaTech ( Chengdu) BioPharmaceutical Corp.

website:http://www.astabiochem.cn/

Contact:+86-15198215156-15198215156

Address:SICHUAN CHENGDU
Fujian Wanke Pharmaceutical Co., LTD.

Contact:+86-598-5026002

Address:Economic development zone,jiangle county
TIANJIN ZHONGXIN CHEMTECH CO.,LTD.

Contact:86-022-89880739

Address:10B, Pan China International Center, No. 931 YingKou Road, TangGu, Tianjin, China, 300451
Hangzhou Hysen Pharma co.,Ltd.

website:http://www.hysenpharma.cn/

Contact:0086-571-88298791

Address:#701,Gudun Road Hangzhou
Chengdu Baishixing Science and Technology Industry Co., Ltd.

website:http://www.cd-bsx.com

Contact:+86-28-88531548

Address:#217,North of Industry Road,Heshan Town,Pujiang County,Chengdu,Sichuan,China.

Relevant to this article

Structural and spectral studies of palladium(II) and platinum(II) complexes derived from N,N,N,N-tetradentate macrocyclic ligands

Doi:10.1016/j.saa.2007.12.051
(2008)
A PSEUDOGUAIANOLIDE AND A HYDROXYGERANYLNEROL FROM KINGIANTHUS PARADOXUS

Doi:10.1016/0031-9422(81)83050-6
(1981)
Ultrastable complexes for in vivo use: A bifunctional chelator incorporating a cross-bridged macrocycle

Doi:10.1039/b406906d
(2004)
Syntheses and studies of multiwarhead siderophore-5-fluorouridine conjugates

Doi:10.1016/S0968-0896(99)00248-5
(1999)
Pd-catalyzed, highly selective C(sp²)-Br bond coupling reactions of o-(or m-, or p-) chloromethyl bromobenzene with arylboronic acids

Doi:10.3390/molecules23020433
(2018)
NUCLEAR MAGNETIC RESONANCE STUDIES OF D-ERYTHROSE 4-PHOSPHATE IN AQUEOUS SOLUTION. STRUCTURES OF THE MAJOR CONTRIBUTING MONOMERIC AND DIMERIC FORMS

Doi:10.1016/S0008-6215(00)85292-1
(1981)

Article Doi