Chemical and Pharmaceutical Bulletin p. 1620 - 1625 (1997)
Update date:2022-08-16
Topics:
Matsuo, Keizo
Sakaguchi, Yusuke
(-)-Vertinolide, a β-tetronic acid derivative isolated from Verticillium intertextum as one of the mycotoxins, was synthesized starting from (R)-lactic acid as the chiral source by using Seebach's chiral self- reproduction method. The β-tetronic acid moiety was constructed by reductive dehydroxylation of α,β-dihydroxybutanolide with samarium(II) iodide and subsequent oxidation.
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