The RuII(OH2)-RuIV(O) Couple in a Ruthenium Complex of 2-(Phenylazo)pyridine: Homogeneous Catalysis of the Oxidation of Water to Dioxygen

DOI: 10.1039/c39820001288

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1288 - 1289 (1982)

Update date:2022-08-31

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Authors:

Goswami, Sreebrata

Chakravarty, Akhil R.

Chakravorty, Animesh

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Article abstract of DOI:10.1039/c39820001288

In acidic solution II(OH2)(py)L2>2+ can be oxidised to IV(O)(py)L2>2+ in a single reversible step (E⁰₂₉₈ = 1.20 V) and the oxidised complex catalyses the dehydrogenation of water to dioxygen in the presence of Ce4+ .

Full text of DOI:10.1039/c39820001288

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