
Chemical and Pharmaceutical Bulletin p. 1929 - 1931 (1998)
Update date:2022-08-25
Topics:
Ueno, Akihiro
Ohashi, Hiroshi
Nakano, Toyoo
Kimura, Kaname
Shimizu, Toshiyuki
Hakojima, Toshio
Iijima, Hiroshi
The crystal structures of sulochrin derivatives, sulochrin triacetate (2) and sulochrin 4-(4'-bromobenzoate) (3), were determined, Triacetyl derivative 2 was in a conformation where the planes of two aromatic rings and the central carbonyl plane were all oblique to each other. Compound 3 was in a conformation where ring B and the central carbonyl planes were co-planar and crossed at a right angle to the ring A plane, suggesting the effect of substituents at ortho positions on conformation of tetra ortho substituted benzophenones.
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