Protodesilylation of 2,6-disubstituted silyphosphinines. Experimental and theoretical study

DOI: 10.1021/jo800105b

Source and publish data:

Journal of Organic Chemistry p. 3258 - 3261 (2008)

Update date:2022-08-11

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Authors:

Blug, Matthias

Piechaczyk, Olivier

Fustier, Marie

Mezailles, Nicolas

Le Floch, Pascal Le

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Article abstract of DOI:10.1021/jo800105b

(Chemical Equation Presented) 2,6-Disilylphosphinines react with HCl in ethereal solution to cleanly yield the corresponding 2,6-unsubstituted derivatives. DFT calculations allowed rationalization of the mechanism of this protodesilylation.

Full text of DOI:10.1021/jo800105b

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