Organic Letters
Letter
Junge, K.; Beller, M. Chem. Commun. 2012, 48, 2683. (f) Das, S.; Addis,
D.; Junge, K.; Beller, M. Chem. - Eur. J. 2011, 17, 12186. (g) Cabrero-
Antonino, J. R.; Alberico, E.; Junge, K.; Junge, H.; Beller, M. Chem. Sci.
2016, 7, 3432. (h) Reeves, J. T.; Tan, Z.; Marsini, M. A.; Han, Z. S.; Xu,
Y.; Reeves, D. C.; Lee, H.; Lu, B. Z.; Senanayake, C. H. Adv. Synth. Catal.
2013, 355, 47. (i) Xie, W.; Zhao, M.; Cui, C. Organometallics 2013, 32,
7440. (j) Pelletier, G.; Bechara, W. S.; Charette, A. B. J. Am. Chem. Soc.
2010, 132, 12817. (k) Sunada, Y.; Kawakami, H.; Imaoka, T.;
Motoyama, Y.; Nagashima, H. Angew. Chem., Int. Ed. 2009, 48, 9511.
tion grants from the NSF (CHE-1048804) and the NIH NCRR
(S10RR025631).
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(15) Performing the reaction at lower temperature and in solvents
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(16) Use of 2 equiv of PhSiH3 enabled the reduction of most substrates
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amine 4.
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in 70% yield, which may indicate that a radical mechanism is not
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this stage.
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D
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