Journal of the Chemical Society. Chemical communications p. 1515 - 1517 (1984)
Update date:2022-08-25
Topics:
Buchanan, J. Grant
Hamblin, Michael R.
Kumar, Ajit
Wightman, Richard H.
Studies with stable isotopes show that D-ribose and L-glutamic acid are direct biosynthetic precursors of showdomycin (1), with carbons 2-5 and the nitrogen of L-glutamate giving rise to the maleimide ring: L-pyroglutamate may be an intermediate.
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Doi:10.1002/hlca.193501801176
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