Reactivities of Stable Rotamers. XIX. Basicities of Rotameric 9-fluorenes and Solvent Effects on Them

DOI: 10.1246/bcsj.60.673

Source and publish data:

Bulletin of the Chemical Society of Japan p. 673 - 682 (1987)

Update date:2022-08-11

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Authors:

Nakamura, Mikio

Oki, Michinori

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Article abstract of DOI:10.1246/bcsj.60.673

The pK_a' values of the trifluoroacetate salts of the title compounds were determined in THF-water (3:2) solution at 25 deg C by potentiometric titration: in every compound examined, basicity of the ap rotamer was higher than of the sp rotamer.D

Full text of DOI:10.1246/bcsj.60.673

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