Journal of the Chemical Society. Chemical communications p. 592 - 594 (1982)
Update date:2022-08-16
Topics:
Shinkai, Seiji
Tsuno, Takaharu
Manabe, Osamu
Reductive desulphonation of 2,4,6-trinitrobenzenesulphonate by N-dodecyl-1-benzyl-1,4-dihydronicotinamide bound to the sodium dodecyl sulphate micelle in D2O solution gave 1,3,5-trinitrobenzene which contained 4.6-5.1percent of deuterium; the result indicates that the reaction proceeds through multi-step hydrogen transfer via a radical ion-pair intermediate and the micelle surface is capable of dissociating the radical ion pair.
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