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| CAS No.: | 123-56-8 |
|---|---|
| Name: | Succinimide |
| Article Data: | 310 |
| Cas Database | |
| Molecular Structure: | |
|
|
|
| Formula: | C4H5NO2 |
| Molecular Weight: | 99.0892 |
| Synonyms: | dihydro-3-pyrroline-2,5-dione;Butanimide;2, 5-Dioxopyrrolidine;Lubrizol 6406;Succinic imide;2,4,6-Trichlorophenyl hydrazine;Succinic acid imide;pyrrolidine-2,5-dione;L 113B;2,5-dioxopyrrolidine;2,5-Pyrrolidinedione;3, 4-Dihydropyrrolidine;3,4-dihydropyrrole-2,5-dione;Succinimide-Sauba;2,5-Diketopyrrolidine; |
| EINECS: | 204-635-6 |
| Density: | 1.274 g/cm3 |
| Melting Point: | 123-125°C |
| Boiling Point: | 288 °C at 760 mmHg |
| Flash Point: | 160 °C |
| Solubility: | Soluble in water and ethanol. Insoluble in ether and chloroform. |
| Appearance: | A white crystalline powder |
| Hazard Symbols: |
 Xi
|
| Risk Codes: | 36/37/38 |
| Safety: | 22-24/25-36-26 |
| Transport Information: | N/A |
| PSA: | 46.17000 |
| LogP: | -0.24820 |
- 123572-59-83-Amino-4,6-difluoro(trifluoromethoxy)benzene
- 1235-77-41-Naphthalenecarboxylicacid, 5-[2-(3-furanyl)ethyl]decahydro-1,4a-dimethyl-6-methylene-,(1R,4aS,5R,8aS)-
- 123577-99-1Ethanone,1-(3,5-difluorophenyl)-
- 1235-82-11-Piperidinepropanol, a-bicyclo[2.2.1]hept-5-en-2-yl-a-phenyl-, hydrochloride (1:1)
- 123583-37-9L-Tyrosinamide,L-isoleucyl-L-lysyl-L-prolyl-L-a-glutamyl-L-alanyl-L-prolylglycyl-L-a-glutamyl-L-a-aspartyl-L-alanyl-L-seryl-L-prolyl-L-a-glutamyl-L-a-glutamyl-L-leucyl-L-asparaginyl-L-arginyl-L-tyrosyl-L-tyrosyl-L-alanyl-L-seryl-L-leucyl-L-arginyl-L-histidyl-L-tyrosyl-L-leucyl-L-asparaginyl-L-leucyl-L-valyl-L-threonyl-L-arginyl-L-glutaminyl-L-arginyl-
- 123593-99-7Isoquinoline,1,2,3,4-tetrahydro-5-methyl-
- 123594-01-48-Fluoro-1,2,3,4-tetrahydroisoquinoline
- 123597-54-61H-Pyrrolo[4,3,2-gh]-1,4-benzodiazonine-5-methanol,2,3,4,5,6,8-hexahydro-1-methyl-2-(1-methylethyl)-9-octyl-, (2R,5R)- (9CI)
- 123597-55-71H-Indole-4-methanol,6-(decylamino)-
- 123599-78-0Acetic acid,2-[[2-methyl-1-(1-oxopropoxy)propoxy](4-phenylbutyl)phosphinyl]-
| Conditions | Yield |
|---|---|
| With acetic anhydride; zinc In toluene at 40 - 86℃; for 48h; Inert atmosphere; chemoselective reaction; | 100% |
| With sulfuric acid In water for 5h; Electrochemical reaction; Flow reactor; chemoselective reaction; | 96% |
| With palladium diacetate; 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane In dichloromethane at 25℃; for 12h; Sealed tube; Inert atmosphere; chemoselective reaction; | 96% |
- 110-89-4
piperidine
A
- 123-56-8
Succinimide
B
- 25116-80-7
N,N'-thiodipiperidine
C
- 6091-44-7
piperidine hydrochloride
| Conditions | Yield |
|---|---|
| With N-chlorothiophthalimide In 1,2-dichloro-ethane at 20 - 25℃; for 2h; | A n/a B 77% C 100% |
| Conditions | Yield |
|---|---|
| With N-iodo-succinimide In benzene for 6h; Product distribution; Irradiation; varying reaction time; | A 99% B 100% |
- 70289-38-2
4-Chloro-1-(4-isopropyl-phenyl)-butan-1-one
A
- 123-56-8
Succinimide
B
- 169280-04-0
1-[4-(1-Bromo-1-methyl-ethyl)-phenyl]-4-chloro-butan-1-one
| Conditions | Yield |
|---|---|
| With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) In tetrachloromethane at 20 - 90℃; for 0.75h; Heating / reflux; Irradiation; | A n/a B 100% |
| Conditions | Yield |
|---|---|
| With carbon monoxide In diethyl ether N2 or Ar, stirred for 3 h; filtered; IR, NMR, GC; | A 100% B n/a |
| Conditions | Yield |
|---|---|
| With hydrogenchloride In methanol passing gaseous HCl through Sn-compd. suspn. at room temp. until ppt. dissolved; soln. evapn. to dryness at room temp., Sn-compd. isolation on residue extn. (hexane); | A 100% B 96% |
| Conditions | Yield |
|---|---|
| With 3,3-dimethyldioxirane In acetone at 0 - 25℃; for 48h; | 99% |
| With oxygen; titanium(IV) oxide In water for 10h; Product distribution; Irradiation; other time, photocatalytic oxidations of lactams and N-acylamines; | |
| With ruthenium(VIII)-oxide |
| Conditions | Yield |
|---|---|
| With N-iodo-succinimide In benzene for 0.916667h; Product distribution; Mechanism; Irradiation; varying reaction time; | A 88% B 99% |
- 14204-24-1
N-(phenylthio)succinimide
- 762-04-9, 123-22-8
Diethyl phosphonate
A
- 123-56-8
Succinimide
B
- 1889-58-3
O,O-diethyl S-phenyl phosphorothioate
| Conditions | Yield |
|---|---|
| In benzene for 20h; Ambient temperature; | A n/a B 99% |
| Conditions | Yield |
|---|---|
| With ammonium peroxydisulfate; silver nitrate In water at 20℃; for 2h; Reagent/catalyst; Temperature; | 99% |
| With iodosylbenzene In dichloromethane for 48h; Ambient temperature; | 27% |
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Chemistry
Molecular Structure of Succinimide (CAS NO.123-56-8):
.png)
IUPAC Name: pyrrolidine-2,5-dione
Empirical Formula: C4H5NO2
Molecular Weight: 99.088
Index of Refraction: 1.479
Surface Tension: 43 dyne/cm
Density: 1.274 g/cm3
Flash Point: 160 °C
Enthalpy of Vaporization: 52.72 kJ/mol
Boiling Point: 288 °C at 760 mmHg
Vapour Pressure: 0.0024 mmHg at 25°C
Synonyms of Succinimide (CAS NO.123-56-8): Butanimide ; 2,5-diketopyrrolidene ; 2,5-diketopyrrolidine ; 2,5-pyrrolidinedione ; 2,5-dioxopyrrolidine ; si;succinic imide
Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| mouse | LD50 | intravenous | 320mg/kg (320mg/kg) | U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#03763, | |
| mouse | LD50 | oral | 11gm/kg (11000mg/kg) | United States Patent Document. Vol. #3639606, | |
| rat | LD50 | oral | 14gm/kg (14000mg/kg) | Medicamentos de Actualidad. Vol. 10, Pg. 224, 1974. |
Consensus Reports
Reported in EPA TSCA Inventory.
Safety Profile
Hazard Codes 
Xi
Risk Statements 36/37/38
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements 22-24/25-36-26
S22:Do not breathe dust.
S24/25:Avoid contact with skin and eyes.
S36:Wear suitable protective clothing.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Specification
Bronopol (CAS NO.52-51-7) is a white crystalline powder,can be used as analytical reagent for the synthesis of drugs and raw materials.it derived from the reaction of succinic acid and ammonia.
The main process is the acid and water during tung ammonia reaction to produce succinimide. Succinic acid can also be put through dropping ammonia to dissolve and react, then heated to 102 ℃ steam to water, further vacuum distillation, when heated to 180 ℃, started to collect fraction succinimide , that was finished.
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